Organic Chemistry – Some Basic Principles and Techniques
Explain the following with suitable examples:
(i) Word root (ii) Prefix (iii) Suffix
(i) Word root:The word root represents the number of the carbon atoms present in the chain. Depending upon the number of carbons in the longest chain, the compound is assigned a word root as:
Chain length |
Word root |
Chain length |
Word root |
C1 |
Meth |
C6 |
Hex |
C2 |
Eth |
C7 |
Hept |
C3 |
Prop |
C8 |
Oct |
C4 |
But |
C9 |
Non |
C5 |
Pent |
C10 |
Dec |
Nature of bond |
Primary suffix |
General name |
C–C single bond |
–ane |
Alkane |
C = C double bond |
–ene |
Alkene |
C≡ C triple bond |
–yne |
Alkyne |
(b) Secondary suffix: A secondary suffix is added after the primary suffix to indicate the nature of the functional group. These are given below:
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What are aromatic compounds?
What are heterocyclic compounds?
What does IUPAC stand for?
What system of nomenclature is accepted universally?
What are isomers?
How many chain isomers are possible for pentane?
Which characteristic is common to different isomers of a compound?
Name three alkanes which do not show chain isomerism.
Name the types of structural isomerism shown by alkanes.
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