The p-Block Elements
(i) Electronegativity: There is no regular change in electronegativity on moving down the group. Down the group, electronegativity first decreases from B to Al and then increases marginally. This is because of the discrepancies in atomic size of the elements.
(ii) Nature of bonds: According to Fajan’s rule, the smaller the cation, the greater is its tendency to form covalent compounds. Thus, with the increase of M3+ ionic radii down the group from B3+ to Tl3+, the tendency of these ions to form covalent compounds decreases. Thus boron forms mostly covalent compounds while other members form ionic compounds also.
(iii) Oxidation states: The general electronic configuration of group 13 elements [Noble gas] is ns2 np1, so these elements are expected to show a uniform oxidation state of + 3. Boron and aluminium show an oxidation state of +3 only, but gallium, indium and thallium, however, show oxidation states of + 1 and +3.
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What is inorganic benzene? Write its formula.
Name a hydride of boron which is used as reducing agent in organic chemistry.
Does a molecule of BH3 exist?
What is relative stability of +1 oxidation state in group 13.
Are all the B-H bonds in diborane equivalent?
What is tincal ?
What is tau or banana bond?
Name two elements used as semiconductors in electronic devices.
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