The s-Block Elements

Question

why is melting point of lithium higher than sodium ?

Answer

It is because they have a strong tendency to lose the valence s-electron to acquire the nearest inert gas configuration. Lithium, however, because of it high ionisation enthalpy forms covalent compounds i.e. alkyl lithium (R – Li), aryl lithium (Ar – Li) etc.
Down the group new shell added which cause shielding effect and thus cause lower the melting point.

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