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The relative reactivities of acyl compounds towards of nucleophilic substitution are in the order of 

  • Acyl chloride> Acid anhydride> Ester> Amide

  • Ester > Acyl chloride> Amide > Acid anhydride

  • Acid anhydride > Amide > Ester> Acyl chloride

  • Acyl chloride > Ester > Acid anhydride > Amide

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