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Question is

Method by which aniline cannot be prepared is 

  • hydrolysis phenyl isocyanide with the acidic solution

  • degradation of benzamide with bromine in alkaline solution

  • reduction of nitrobenzene with H2/Pd in ethanol

  • potassium salt of phthalimide treated with chlorobenzene followed by the hydrolysis with aqueous NaOH solution

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