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Vapour pressures of pure acetone and chloroform at 328 k are 741.8 nm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot Ptotal , Pchlroform and Pacelone as a function of Xactone. The experimental date observed for different composition of mixture is:
100 x xacetone
0
11.8
23.8
36.0
50.8
58.2
64.5
72.1
Pacetone / mm Hg
54.9
110.1
202.4
327.7
405.9
454.1
521.1
Pchloroform/ mm Hg
632.8
548.1
469.4
359.7
257.7
193.6
161.2
120.7
Plot this data also on the same graph paper, indicate whether it has positive deviation or negative deviation from the ideal solution.