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Wave Optics

Question
CBSEENPH12039567

The potential energy function for the force between two atoms in a diatomic molecule is approximately given by straight U left parenthesis straight x right parenthesis space equals space straight a over straight x to the power of 12 minus straight b over straight x to the power of 16 where a and b are constants and x is the distance between the atoms. If the dissociation energy of the molecule is D = [U(x = ∞) – Uat equilibrium], D is

  • b2/2a

  • b2/12a

  • b2/4a

  • b2/6a

Solution

C.

b2/4a

The potential energy for diatomic molecule is 
straight U left parenthesis straight x right parenthesis space equals space straight a over straight x to the power of 12 minus straight b over straight x to the power of 6
straight U space left parenthesis straight x space equals space infinity right parenthesis space equals space 0
As comma space straight F space equals space minus space dU over dx space equals space minus space open square brackets fraction numerator 12 straight a over denominator straight x to the power of 13 end fraction plus fraction numerator 6 straight b over denominator straight x to the power of 7 end fraction close square brackets
At space equilibrium comma space straight F space equals space 0
therefore space straight x to the power of 6 space equals space fraction numerator 2 straight a over denominator straight b end fraction
therefore space straight U subscript at space equilibrium end subscript space equals space straight a over open parentheses begin display style fraction numerator 2 straight a over denominator straight b end fraction end style close parentheses squared space minus space fraction numerator straight b over denominator open parentheses begin display style fraction numerator 2 straight a over denominator straight b end fraction end style close parentheses end fraction space equals space fraction numerator negative straight b squared over denominator 4 straight a end fraction
therefore space straight D space equals space left square bracket space straight U space left parenthesis straight x equals space infinity right parenthesis minus straight U subscript at space equilibrium space right square bracket space end subscript space equals space fraction numerator straight b squared over denominator 4 straight a end fraction