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Kinetic Theory

Question
CBSEENPH11026451

1 mole of H2 gas is contained in a box of volume V  = 1.00 m3  at  T = 300 K. The gas is heated to a temperature of  T = 3000 K  and the gas gets converted to a gas of hydrogen atoms. The final pressure would be (considering all gases to be ideal)

  • same as the pressure initially

  • 2 times the pressure initially

  • 10 times the pressure initially

  • 20 times the pressure initially

Solution

D.

20 times the pressure initially

According to Ideal gas equation

              PV  = nRT

             P2 V1T2 = P1 V1T1

⇒           P2P1 = V1V2 T2T1

Here T2 = 3000 K,  T1 = 300 K

Since H2 splits into hydrogen atoms, therefore volume become half 

i.e           V212 V1

∴               P2P1 = V112 V1

∴                 P2P1 = 20