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Mechanical Properties Of Fluids

Question
CBSEENPH11019785

Three moles of an ideal gas at 300K are isothermally expanded to five times its initial volume and then heated at this constant volume so that the pressure is raised to its initial value before expansion. In the whole process 8314kJ heat is required. Find γ of the gas.

Solution
Let P and V be the initial pressure and volume.
P' and V' be the pressure and volume after isothermal expansion. 
Given,
Number of poles, n = 3
Temperature, T = 300K 
Final volume, straight V apostrophe space equals space 5 straight V space left parenthesis Given right parenthesis 
Perfect gas equation for isothermal process, 
             "<pre 
rightwards double arrow         straight P apostrophe space equals space straight P fraction numerator straight V over denominator straight V apostrophe end fraction equals straight P over 5 
During isothermal expansion, the change in internal energy of the gas is zero.
Therefore the work done by the gas is equal to heat absorbed by gas.
i.e.
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        equals 3 cross times 8.314 cross times 300 left parenthesis Ln 5 right parenthesis 
      space space equals 12042.8 straight J
Now the gas is heated at constant volume, therefore the process is isochoric.  
The initial and final values of thermodynamic variables (represented by prime and double prime superscripts) during isobaric process are given as, 
       space straight T apostrophe space equals space 300 straight K comma space space space space space space space space straight P apostrophe space equals space straight P divided by 5 comma space space space space space straight V apostrophe space equals space 5 straight V
straight T " space equals space ? space space space space space space space space space space space space space space space space straight P " space equals space straight P comma space space space space space space space space space straight V " space equals space 5 straight V 
Gas equation for adiabatic process is, 
                       space fraction numerator straight T " over denominator straight T apostrophe end fraction equals fraction numerator straight P " over denominator straight P apostrophe end fraction 
rightwards double arrow     straight T " space equals 5 straight T apostrophe space equals space 1500 straight K 
According to first law of thermodynamics, 
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For isochoric process, increment straight W equals 0. space 
Thus, 
            space increment straight Q subscript 2 space equals space nC subscript straight v increment straight T space

space space space space space space space space space space equals space 3 cross times straight C subscript straight v cross times 1200 space

space space space space space space space space space space equals space 3600 straight C subscript straight v 
Total heat absorbed by gas during the process, 
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          83140 equals 12042.8 plus 4500 straight C subscript straight v 
rightwards double arrow         space space space straight C subscript straight v space equals space 19.75 space straight J divided by mol divided by straight K 
                    equals 4.7 space cal divided by mol divided by straight K 
Now,
Ratio of specific heat is, 
space space straight gamma space equals space straight R over straight C subscript straight v plus 1 equals fraction numerator 2 over denominator 4.7 end fraction plus 1 space equals space 1.426