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Mechanical Properties Of Fluids

Question
CBSEENPH11019779

An ideal gas has a specific heat C = 2.5R. The gas is kept in a closed vessel of volume 0.008m3 at a temperature 300K and a pressure 1.5x106N/m2. If 6000 cal of heat is supplied to the gas, then find the final temperature and pressure of the gas. R = 2 cal/mole/K.

Solution
Volume of the gas is constant. Therefore the work done by gas is zero.
 i.e. W = 0 
Now, according to first law of thermodynamics, 
                increment straight Q space equals space increment straight U plus increment straight W equals increment straight U 
The change in internal energy of an ideal gas is given by, 
                increment straight U space equals space straight n space straight C subscript straight v increment straight T 
Also from gas equation,
                     PV equals nRT 
We have,
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rightwards double arrow      increment straight T space equals space fraction numerator increment straight Q over denominator straight C subscript straight v end fraction RT over PV 
Here,    
Heat space change comma space increment straight Q space equals space 6000 space cal comma space

Pressure comma space straight P space equals space 1.5 cross times 10 to the power of 6 straight N divided by straight m squared space

Temperature comma space straight T space equals space 300 straight K comma space

Volume comma space straight V space equals space 0.008 space straight m cubed space

Universal space gas space constant comma space straight R space equals space 2 space cal divided by mole divided by straight K space

Specific space heat comma space space straight C subscript straight v space equals space 2.5 straight R space equals space 5 space cal divided by mole divided by straight K space

therefore space space space increment straight T space equals space 6000 over 5 cross times fraction numerator 8.4 cross times 300 over denominator 1.5 cross times 10 to the power of 6 cross times 0.008 end fraction space

space space space space space space space space space space space space space space equals space 252 straight K 
Final temperature,
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From perfect gas equation, at constant volume 
            fraction numerator straight P apostrophe over denominator straight P end fraction equals fraction numerator straight T apostrophe over denominator straight T end fraction 
rightwards double arrow      space space space straight P apostrophe space equals straight P fraction numerator straight T apostrophe over denominator straight T end fraction equals 1.5 cross times 10 to the power of 6 552 over 300 
                equals 2.76 cross times 10 to the power of 6 space straight N divided by straight m squared 
T' and P' are the pressure and temperature of the gas respectively.