Question
By using first law of thermodynamics, find the change in internal energy during boiling of liquids.
Solution
Let the latent heat of vaporisation of a liquid of mass m at its boiling temperature be L.
Let Vℓ be the volume of liquid and Vv be the volume of vapours and let evaporation take place at constant pressure P.
According to the first law of thermodynamics,
This is the required expression for change in internal energy.