Sponsor Area

Mechanical Properties Of Fluids

Question
CBSEENPH11019500

(a) Can Cp < Cv?

(b) Can a system which is not in thermal equilibrium be in thermal equilibrium at a later time? Give an example.

Solution

(a) Yes, when water is heated from 0°C to 4°C then Cp < Cv , because water contracts when heated from 0°C to 4°C. Water exhibits anomalous behaviour.

(b) Yes, when we add a hot piece of metal into water, the temperature of the metal piece starts decreasing and that of water starts increasing. After some time temperature of both becomes equal and hence thermal equilibrium is attained.