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Mechanical Properties Of Fluids

Question
CBSEENPH11019264

Derive an expression for the pressure of a gas.

Solution
The molecules of gas are in random motion. So,  they exert pressure on the walls of the container and strike with the walls of the container. Therefore, they exert thrust or force on the wall.  
The thrust exerted by molecules per unit area of the wall of the container is called pressure. 
 
Consider a cubical vessel of side  is enclosing an ideal gas. 
Let m be the mass of gas molecules. 
Let v1 be the velocity of one of the gas molecules. 
If v1x , v1y, v1z are the components of v1
Then, 
straight v subscript 1 space space equals space straight v subscript 1 straight x end subscript space straight i with hat on top space plus space straight v subscript 1 straight y end subscript space straight j with hat on top space plus straight v subscript 1 straight z end subscript space straight k with hat on top space

straight v subscript 1 to the power of 2 space end exponent equals space space straight v subscript 1 straight x end subscript squared space plus space space straight v subscript 1 straight y end subscript squared space plus space straight v subscript 1 straight z end subscript squared space 
Let this molecule approaches the face towards L. 
Before collision with the walls, momentum is given by, 
straight p subscript 1 space equals space mv subscript 1 space equals space mv subscript 1 straight x end subscript space straight i with hat on top space plus space space mv subscript 1 straight y end subscript straight j with hat on top space plus space mv subscript 1 straight z end subscript space straight k with hat on top space 
Since molecule collides with face L due to X-component of motion, therefore, due to collision only X-component of momentum will change. 
Since collision is elastic, therefore momentum after collision is given by, 
stack straight p subscript 1 apostrophe with rightwards arrow on top space equals space minus mv subscript 1 straight x end subscript straight i with hat on top space plus space mv subscript 1 straight y end subscript straight j with hat on top plus mv subscript 1 straight z end subscript straight k with hat on top 
Due to collision, the change in momentum of molecule is, 
space stack straight p subscript 1 apostrophe with rightwards arrow on top minus stack straight p subscript 1 with rightwards arrow on top space equals space minus 2 mv subscript 1 straight x end subscript straight i with hat on top
Let n be the number of molecules per unit volume.
Since the molecules approach towards face L with velocity v1x, therefore, the molecules lying in the cylinder of length v1x and area of cross-section A may collide with face L on area in one second. 
Since molecular motion is random, therefore, it is logical to suppose only half of the molecules that lie in cylinder will strike the area A in one second. 

Number space of space molecules space that space strike space on space
area space straight A space of space face space straight L space in space one space second space equals space 1 half left parenthesis nAv subscript 1 straight x end subscript right parenthesis space

Change space in space momentum space of space striking space molecules
on space area space straight A space in space one space second space equals space Change space in space momentum
of space one space molecule right parenthesis space straight X space left parenthesis Number space of space molecules space striking space per space sec right parenthesis

space space space equals space minus space 2 straight m space straight v subscript 1 straight x end subscript straight i with hat on top space cross times space 1 half left parenthesis nAv subscript 1 straight x end subscript right parenthesis space equals space minus nm space Av subscript 1 straight x end subscript squared space straight i with hat on top space

Since comma space velocity space of space all space the space molecules space is space not space the space same comma space
therefore comma space straight v subscript 1 straight x end subscript squared space must space be space replaced space by space mean space square space
velocity space straight i. straight e. space straight v with rightwards harpoon with barb upwards on top space subscript straight x squared space

Therefore comma space

Change space in space momentum space of space colliding space molecules
in space one space second space equals space minus nmA straight v with rightwards harpoon with barb upwards on top space subscript straight x squared space straight i with hat on top space

But comma space change space in space momentum space in space one space second space is space force.

Therefore comma space

Force space on space colliding space molecules space equals space minus mA straight v with rightwards harpoon with barb upwards on top space subscript straight x squared space straight i with hat on top space
According to Newton’s third law of motion, to every action, there is an equal and opposite reaction.
Therefore, gas molecules exert an equal and opposite force on area A of face L as experienced by gas molecules. 
Force on area A of face L, straight F subscript straight x equals nmA straight v with rightwards arrow on top subscript straight x squared 
Therefore pressure on face L is, 
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Similarly, 
straight P subscript straight y space equals space nmA space straight v with bar on top subscript straight y squared space

straight P subscript straight z space equals space nmA space space straight v with bar on top subscript straight z squared space

Since comma space gas space exerts space equal space pressure space on space all space the space
walls space of space the space container comma space

straight P subscript straight x space equals space straight P subscript straight y space equals straight P subscript straight z space equals space straight P thin space

rightwards double arrow space straight P space equals space fraction numerator straight P subscript straight x space plus space straight P subscript straight y space plus straight P subscript straight z over denominator 3 end fraction

space space space space space space space space space equals space 1 third space nm space left parenthesis straight v with bar on top subscript straight x squared space plus space space straight v with bar on top subscript straight y squared space plus straight v with bar on top subscript straight z squared space right parenthesis space

space space space space space space space space space space equals space 1 third space nm space straight v with bar on top squared space equals space 1 third space straight rho space straight v subscript straight r squared space space space space space space space left square bracket because space nm space equals space straight rho right square bracket

where comma space straight v subscript straight r squared space is space the space mean space square space velocity space of space
gas space molecules. space