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Units And Measurement

Question
CBSEENPH11016525

What are the dimensions of Vander Waal’s constant? 

Solution
 Vander Waal's gas equation is
space space space space space space space open square brackets straight P plus straight a over straight v squared close square brackets open parentheses straight v minus straight b close parentheses equals nRT
Now, according go to the principle of homogeneity of  dimensions, straight P space and space straight a over straight r squared have same dimensions.
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#6 {main}</pre>
   rightwards double arrow  a = PV
This dimesnsional formula of a is 
space space straight a space equals space open square brackets straight M to the power of 1 straight L to the power of negative 1 end exponent straight T to the power of negative 2 end exponent close square brackets open square brackets straight M to the power of 0 straight L to the power of 6 straight T to the power of 0 close square brackets equals open square brackets bold M to the power of bold 1 bold L to the power of bold 5 bold T to the power of bold minus bold 2 end exponent close square brackets
Similarly b = v
Therefore dimensional formula of b is, 
straight b space equals space open square brackets bold M to the power of bold 0 bold L to the power of bold 3 bold T to the power of bold 0 close square brackets