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Control And Coordination

Question
CBSEENSC10010993

CaSO4.12H2O is used as plaster of Paris but CaSO4 is used as a drying agent and cannot replace plaster of Paris. Explain.

Solution

Anhydrous calcium sulphate (CaSO4) takes up water readily and forms hydrated salt and so is used as a drying agent,

CaSO4 + 2H2O → CaSO4 · 2H2O

CaSO4.12H2O has a particular crystal structure which imparts property of setting and hardening on mixing with water. CaSO4 cannot replace plaster of paris because on mixing with water it does not acquire the property of setting and hardening.