is used as plaster of Paris but CaSO4 is used as a drying agent and cannot replace plaster of Paris. Explain.
Anhydrous calcium sulphate (CaSO4) takes up water readily and forms hydrated salt and so is used as a drying agent,
CaSO4 + 2H2O → CaSO4 · 2H2O
has a particular crystal structure which imparts property of setting and hardening on mixing with water. CaSO4 cannot replace plaster of paris because on mixing with water it does not acquire the property of setting and hardening.