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Control And Coordination

Question
CBSEENSC10010990

Give the properties of plaster of Paris.

Solution

On heating gypsum at 373K, it loses water molecule and becomes calcium sulphate hemihydrate(CaSO4.1/2H2O).

Properties of plaster of Paris:
(i) It is a white powder.
(ii) Setting property: When wetted with water, this forms a solid plastic mass and heat is given out during this process and finally a hard porous mass results within 10-15 minutes. This involves two steps. Firstly, water is absorbed to form orthorhombic dihydrate and change to monoclinic, when the plaster hardens, thus setting takes place.

CaSO4.12H2O setting        H2O CaSO4.2H2O      Hardening           CaSO4. 2H2O                                  Orthohombic                            Monoclinic                                     dihydrate                                 dihydrate