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Chemical Kinetics

Question
CBSEENCH12011452

A mixture of 2.3 g formic acid and 4.5 g oxalic acid is treated with conc. H2SO4. The evolved gaseous mixture is passed through KOH pellets. Weight (in gram) of the remaining product at STP will be

  • 1.4

  • 3.0

  • 4.4

  • 2.8

Solution

D.

2.8

HCOOH Dehydrating AgentH2SO4 CO +   H2O Water is abosrbed by sulphuric acid(Moles)i = 2.346 = 120          0           0(moles)f =  0                         120     120H2C2O4        H2SO4         CO + CO2 +H2OWater is abosrbed by sulphuric acid(Moles)i = 4.590 = 120          0           0       0(moles)f =  0                         120     120        120

CO2 is absorbed by KOH.
So the remaining product is only CO.
moles of CO formed from both reaction
=120+120 = 110

Let mass of CO = moles x molar mass

 =  = 110 x  28