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Solutions

Question
CBSEENCH12011360

0.5 Molal aqueous solution of aweak acid (HX) is 20% ionised. If Kf for water is1.86 K kg mol-1, the lowering in freezing point of the solution is:

  • -1.12 K 

  • 0.56 K 

  • 1.12 K 

  • -0.56 K 

Solution

C.

1.12 K 

stack stack HX space with weak space acid below with 1 minus alpha below space space rightwards harpoon over leftwards harpoon space space space stack stack space straight H to the power of plus with 0 below space with straight alpha below plus stack space stack straight X to the power of minus end exponent with 0 below with straight alpha space below

straight alpha space equals space 20 percent sign space dissociation
space straight i space equals space 1 space minus space straight alpha space plus space straight alpha space plus straight alpha
space equals space 1 space plus space straight alpha space equals space 1 space plus space 0.2 space equals space 1.2
increment straight T subscript straight f space equals space straight i space straight x space straight K subscript straight f space straight x space straight m
space equals space 1.2 space straight x space 1.86 space straight K space kg space mol to the power of negative 1 end exponent space straight x space 0.5
space equals space 1.12 space straight K