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The D-And-f-Block Elements

Question
CBSEENCH12011356

Which one of the following ions is the most stable in aqueous solution?

  • Cr3+

  • V3+

  • Ti3+

  • Mn3+

Solution

C.

Ti3+

Stability to transition metal ion is directly proportional to the unpaired electron. The exactly half filled and completely filled d - orbitals are extra stable.
Cr3+ (21) = 3d3 4s0 -3 unpaired electrons
V3+ (20) = 3d2 4so -2 unpaired electrons
Ti3+ (19) = 3d1 4s0 -1 unpaired electron
Mn3+ (22) = 3d4 4so - 4 unpaired electrons
So,  Mn3+ ion is most stable in aqueous solution.