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The D-And-f-Block Elements

Question
CBSEENCH12011206

Acidified K2Cr2O7 solution turns green when Na2SO3 is added to it. This is due to the formation of 

  • CrO42-

  • Cr2(SO3)3

  • CrSO4

  • Cr2(SO4)3

Solution

D.

Cr2(SO4)3

K2Cr2O7 +3Na2SO3 + 4H2SO4 → 3Na2SO4 +K2SO4 + Cr(SO4)3 +4H2O
Chromium(III) sulfate gives green colour.