+91-8076753736[email protected]
logo
logo
-->

Amines

Question
CBSEENCH12011138
Wired Faculty App

Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80-1000C forms which one of the following products?

  • 1,2-dinitrobenzene

  • 1,3- dinitrobenzene

  • 1,4-dinitrobenzene

  • 1,2,4-trinitrobenzene

Solution

B.

1,3- dinitrobenzene

NO2 group being electron withdrawing reduces electron density at output positions. Hence, now the meta-position becomes electron rich on which the electrophile (nitronium ion) attacks during nitration.
HNO3 +H2SO4 ---> H2NO3+ +HSO-4 +H2O +NO2+


Some More Questions From Amines Chapter

How will you convert Benzene into N, N-dimethylaniline?

Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH

Arrange the following in increasing order of their basic strength:
C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2

Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5 CH2NH2

Write reactions of the final alkylation product of aniline with excess of methyl iodide in the presence of sodium carbonate solution.

Write chemical reaction of aniline with benzoyl chloride and write name of the product obtained.

Write structures of different isomers corresponding to the molecular formula C3H9N. Write IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.

Mock Test Series

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation