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The D-And-f-Block Elements

Question
CBSEENCH12011029

When copper is heated with conc. HNO3 it produces

  • Cu(NO3)2 and NO

  • Cu(NO3)2, NO and NO2

  • Cu(NO3)2 and N2O

  • Cu(NO3)2 and NO2

Solution

D.

Cu(NO3)2 and NO2

Nitric acid acts as an oxidising agent while reacting with copper.
i) when copper reacts with dilute nitric acid it forms,
3Cu + 4HNO3(dilute) --> 3Cu(NO3)2 +2NO +4H2O
ii) When copper reacts with concentrated nitric acid it forms,
Cu +4HNO3(conc.) ---> Cu(NO3)2 +NO2 +2H2O