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General Principles And Processes Of Isolation Of Elements

Question
CBSEENCH12010657

The metal that cannot be obtained by electrolysis of an aqueous solution of its salts is

  • Ag

  • Ca

  • Cu

  • Cr

Solution

C.

Cu

Higher the position of the element in electrochemical series more difficult is the reduction of its cations.
 If Ca2+ (aq) is electrolyzed, water is reduced in preference to it. Hence, It cannot be reduced electrically from their aqueous solution.
Ca2+ (aq) + H2O → Ca2+ +OH- +H2