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Amines

Question
CBSEENCH12010378
Wired Faculty App

Write the structures of A, B and C in the following:

straight i right parenthesis space straight C subscript 6 straight H subscript 5 space minus CONH subscript 2 space rightwards arrow with Br subscript 2 divided by aq. KOH on top space straight A space rightwards arrow from 0 minus 5 to the power of 0 straight C to NaNO subscript 2 space plus HCl of space straight B space rightwards arrow with KI on top space straight C ii right parenthesis space CH subscript 3 minus Cl space rightwards arrow with KCN on top space straight A space rightwards arrow with LiAlH subscript 4 on top space straight B rightwards arrow from increment to CHCl subscript 3 space plus alc. space KOH of space straight C

Solution
straight i right parenthesis space straight C subscript 6 straight H subscript 5 minus CONH subscript 2 space rightwards arrow with Br divided by aq. KOH on top space stack bold C subscript bold 6 bold H subscript bold 5 bold NH subscript bold 2 with straight A below stack straight C subscript 6 straight H subscript 5 NH subscript 2 space with straight A below space rightwards arrow from 0 minus 5 to the power of 0 space straight C to NaNO subscript 2 space plus HCl of space stack bold C subscript bold 6 bold H subscript bold 5 bold N subscript bold 2 bold Cl with straight B below space rightwards arrow with KI on top space stack bold C subscript bold 6 bold H subscript bold 5 bold I with bold C below ii right parenthesis space CH subscript 3 minus Cl space rightwards arrow with KCN on top space stack bold CH subscript bold 3 bold CN with bold A below space rightwards arrow with LiAlH subscript 4 on top bold space stack bold CH subscript bold 3 bold CH subscript bold 2 bold minus bold NH subscript bold 2 with bold B below stack CH subscript 3 CH subscript 2 minus NH subscript 2 with straight B below space rightwards arrow from increment to CHCl subscript 3 space plus alc. space KOH of space stack bold CH subscript bold 3 bold CH subscript bold 2 bold NC with bold C below

Some More Questions From Amines Chapter

How will you convert Benzene into N, N-dimethylaniline?

Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH

Arrange the following in increasing order of their basic strength:
C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2

Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5 CH2NH2

Write reactions of the final alkylation product of aniline with excess of methyl iodide in the presence of sodium carbonate solution.

Write chemical reaction of aniline with benzoyl chloride and write name of the product obtained.

Write structures of different isomers corresponding to the molecular formula C3H9N. Write IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.

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