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General Principles And Processes Of Isolation Of Elements

Question
CBSEENCH12010028

Describe Van Arkel method to obtain metals of high purity.

Solution

Van arkel developed a method is based on the thermal decomposition and is used for getting pure metal. In this method, the metal is converted into a volatile compound, while impurities remain unaffected during compound formation. The resulting compound is then decomposed to get pure metal. for example this method is used for refining Zirconium or Titanium:

For example

Ti      +    2I2 → TiI4(gas) + heat → Ti +2I2
impure                    compound                 pure