Describe Van Arkel method to obtain metals of high purity.
Van arkel developed a method is based on the thermal decomposition and is used for getting pure metal. In this method, the metal is converted into a volatile compound, while impurities remain unaffected during compound formation. The resulting compound is then decomposed to get pure metal. for example this method is used for refining Zirconium or Titanium:
For example
Ti + 2I2 → TiI4(gas) + heat → Ti +2I2
impure compound pure