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The D-And-f-Block Elements

Question
CBSEENCH12010073

How would you account for the following?


Transition metals form coloured compounds.

Solution

In the presence of ligands, the d-orbitals of transition metal ions split up into two sets of orbitals having different energies. Thus, the transition of electrons takes place from one set to another. The energy required for these transitions is quite less and falls in the visible region of radiation. The ions of transition metals absorb the radiation of a particular wavelength and the rest is reflected, imparting colour to the solution.