Why does bromination of aniline, even under very mild conditions give 2, 4, 6- tribromo aniline instantaneously?

Solution

This high reactivity of aniline is due to the fact that, in addition to other resonating structures that stabilizes the intermediate carbonium ion in aromatic electrophilic substitution, the following two structures are also formed due to the interaction of nitrogen lone pair of an electron with the positively charged ring. This also contributes to the stability of the intermediate in o, p-bromination.

Some More Questions From Amines Chapter

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Amines

Why does bromination of aniline, even under very mild conditions give 2, 4, 6- tribromo aniline instantaneously?

Some More Questions From Amines Chapter

Classify the following amines as primary, secondary or tertiary:

Classify the following amines as primary, secondary or tertiary:

Classify the following amines as primary, secondary or tertiary:
(C₂H₅)₂CHNH₂

Classify the following amines as primary, secondary or tertiary:
(C₂H₅)₂NH

Write structures of different isomeric amines corresponding to the molecular formula C₄H₁₁N.

Write IUPAC names of all the isomers.

What type of isomerism is exhibited by different pairs of amines?

How will you convert Benzene into N, N-dimethylaniline?

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

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For Daily Free Study Material Join wiredfaculty

Amines

Why does bromination of aniline, even under very mild conditions give 2, 4, 6- tribromo aniline instantaneously?

Some More Questions From Amines Chapter

Classify the following amines as primary, secondary or tertiary:

Classify the following amines as primary, secondary or tertiary:

Classify the following amines as primary, secondary or tertiary:(C2H5)2CHNH2

Classify the following amines as primary, secondary or tertiary:(C2H5)2NH

Write structures of different isomeric amines corresponding to the molecular formula C4H11N.

Write IUPAC names of all the isomers.

What type of isomerism is exhibited by different pairs of amines?

How will you convert Benzene into N, N-dimethylaniline?

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Classify the following amines as primary, secondary or tertiary:
(C₂H₅)₂CHNH₂

Classify the following amines as primary, secondary or tertiary:
(C₂H₅)₂NH

Write structures of different isomeric amines corresponding to the molecular formula C₄H₁₁N.