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Amines

Question
CBSEENCH12008943
Wired Faculty App

Given the reaction:
straight R subscript 2 NH space rightwards arrow with NaNO subscript 2 plus HCl on top straight R subscript 2 straight N minus straight N space equals space straight O space plus space NOCl space plus space straight H subscript 2 straight O 

Why is the productstraight R subscript 2 straight N space minus space NO insoluble in aqueous HCl?

Solution
The line pair on amine nitrogen is delocalized with the nitroso group. As a result R2N—NO does not show basic properties and hence insoluble in aqueous HCl.

Some More Questions From Amines Chapter

Classify the following amines as primary, secondary or tertiary:
(C2H5)2NH

Write structures of different isomeric amines corresponding to the molecular formula C4H11N.

Write IUPAC names of all the isomers.

What type of isomerism is exhibited by different pairs of amines?

How will you convert Benzene into N, N-dimethylaniline?

Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH

Arrange the following in increasing order of their basic strength:
C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2

Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5 CH2NH2

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