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Amines

Question
CBSEENCH12008917

The amino group in ethyl amine is basic, whereas that in acetamide, it is not basic. Why?

Solution
In acetamide, delocalization of lone pair of an electron on N due to resonance gives rise to lesser availability of a lone pair of the electron for coordination whereas in amines no such resonance exists.

Thus, amino group in ethyl amine is basic.