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Alcohols, Phenols And Ethers

Question
CBSEENCH12008306

Give a chemical test to distinguish between: 2-pentanol and 3-pentanol.

Solution
2-pentanol on oxidation gives methylketone.

This compound has a CH3C = O group.
Therefore, it will form iodoform (CHI3) with iodine and alkali on warming. Iodoform is a yellow crystalline substance.

3-pentanol does not show this test.