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The P-Block Elements

Question
CBSEENCH12006827

Give reasons for the following:
NO2 demerises to form N2O4

Solution
NO2 is an odd electron molecule i.e., it has one unpaired electron. Such molecules are highly reactive and tend to form a dimer by pairing of the unpaired electrons. Thus get stablity, Therefore NO2, dimerises to form N2O4 which contains a N-N single bond.