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Surface Chemistry

Question
CBSEENCH12006458

Write a mathematical expression showing relationship between the amount of solute adsorbed per unit mass of the solid adsorbent and the concentration of the solute in solution.

Solution
Answer:

Freundlich adsorption isotherm: Freundlich gave an
empirical relationship between the quantity of gas adsorbed by unit mass of solid adsorbent and pressure at a particular temperature. The relationship can be expressed by the following equation


xm=kP1/η.

where x is mass of the gas absorbedon mass m of the absorbent at pressure P 
k and n are constant depends on the nature of adsorbent and gas at particular temperature.