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Chemical Kinetics

Question
CBSEENCH12006292

During nuclear explosion, one of the products is 90Sr with half-life of 28.1 Years. If 1 μg of 90Sr was absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not lost metabolically. 

Solution
All radioactive decay are first order process.
 decay constant.

     λ=  0.693t1/2 = 0.69328.1 = 0.0247 year-1

(i) where t  = 10 years,

         λ = 2.303tlogN0Nt = 10 yearsN0 = 1 microgram      = 1×10-6g, N = ?10 = 2.3030.0247log1×10-6N

log1×10-6N=10×0.02472.303=0.1072        1 × 10-6N =Antilog 0.1072 = 1.1280      N = 1×10-61.1280 = 0.7842 log


(ii) 
       t =60 years         60 = 2.3030.0247log1×10-6Nlog1×10-6N = 60×0.02472.303 = 0.6435      1×10-6N = 60×0.02472.303 = 0.6435      1×10-6N = Antilog 0.6453 = 4.400         N = 1×10-64.400 = 0.227 μg


Thus, after 10 years and 60 years, 0.7842 log and 0.227 log of 
90Sr will be left as undecayed.