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Chemical Kinetics

Question
CBSEENCH12006291

The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the C14 activity found in living tree. Estimate the age of the sample or calculate the age of the artefact.

Solution
We have given
t
1/2 = 5730 years

NN0 = 80% = 0.80

Decay constant,

              λ = 0.693t1/2 = 0.6935730   = 1.21 × 10-4 year-1

All radioactive nuclear decay are first order process.

Therefore, decay constant,

                  λ = 2.03tlogN0Nλ = 2.30tlog108

or       

             time, t = 2.303λlog 1.25            = 2.3031.21 × 10-4 log 1.25            = 2.3031.21×10-4×0.0969            = 1845 years.Age of sample = 1845 years.