-->

Chemical Kinetics

Question
CBSEENCH12006145

Time required to decompose SO2 Cl2 to half its initial amount is 60 minutes. If the decomposition is a first order reaction, calculate the rate constant of the reaction.

Solution
Given that
half life, t
1/2 = 60 min = 60 x 60 = 3600 sec (1 min = 60 sec)
The formula of half life for the a 1st order

reaction,
For a first order reaction.


t = 2.303k log 1a-xt1/2 = 60 minutes         = 60 × 60 sec. = 360 sec.   k = 0.6933600 sec. = 1.925 × 10-4 s-1