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The Solid State

Question
CBSEENCH12005503

An element a crystallises in fcc structure. 200 g of this element has 4.12 x 1024atoms. The density of A is 7.2 g cm-3. Calculate the edge length of the unit cell?

Solution
solution:
we have given that
mass = 200g
density = 7.2 g cm-3
NA = 4.12 x 1024
Z = 4 
by using the following equation,
 
ρ = z× Ma3× NA
                     

               a3 = Z×Md×N
                 

         = 4×2007.2×4.12×1024= 80029.664×10-24


            a3 = 26.968×10-24a = 2.997×10-8a = 299.7 pm.
 
hence the edge length is 299.7pm