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The Solid State

Question
CBSEENCH12005591

Tungsten has a density of 19.35 g cm–3 and the length of the side of the unit cell is 316 pm. The unit cell is a body centred unit cell. How many atoms does 50 grams of the element contain ?

Solution

we have given,

density =19.35 g cm-3
edge length =316 pm
Number of unit cell =2 (BCC)
Mass =?

Thus,
Length of edge of the unit cell = 316 pm =316 x 10-10cmvolume of the unit cell = (316 x 10-10cm)3                              = 3.2 x 10-23 cm3/unit cellDensity  =atomic mass x Zunit cell volume  x NAAtomic mass = Density xUnit volume  xNAZ=19.35 x 3.2 x 10-23 x 6.023 x 10 232 =186.5 g/ molAs 186.5 g the element contain NA atoms   = 6.023 x 10 23 atomsso 50g of the element contain NA atoms =6.023 x 1023 x 50186.5=1.614 x 1023 atoms