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The Solid State

Question
CBSEENCH12005581

Calculate the efficiency (percentage of volume occupied and unoccupied) of packing in case of a metal crystal for simple cubic.

Solution

Let ‘a’ be the edge length of the unit cell and r be the radius of sphere.

As sphere are touching each other

Therefore a = 2r

No. of spheres per unit cell = 1/8 × 8 = 1 

Volume of the sphere = 4/3 πr3 

Volume of the cube = a3= (2r)3 = 8r3

∴ Fraction of the space occupied = 1/3πr3 / 8r3 = 0.524

∴ % occupied = 52.4 %