If the radius of the octahedral void is r and radius of the atoms in close packing is R, derive relation between r and R.

Solution

An octahedral void is shown in Fig. Though an octahedral void is surrounded by six spheres, only four are shown. The spheres present above and below the void are not shown. Let us assume that the edge length of the unit cell is a cm and raius of octahedral void is r and the radius of sphere is R.

In the given figure, let an sphere having centre ‘O’ is fitted in the octahedral void.
As given, radius of the sphere fitted in the octahedral void = r

And radius of the atoms in close packing = R

Some More Questions From The Solid State Chapter

Why is glass considred a super-cooled liquid?

Refractive index of a solid is observed to have the same value along all directions. Comment on the nature of this solid. Would it show clevage property?

Classify the following solids in different categories based on the nature of intermolecular forces operating in them:
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The Solid State

If the radius of the octahedral void is r and radius of the atoms in close packing is R, derive relation between r and R.

Some More Questions From The Solid State Chapter

Why is glass considred a super-cooled liquid?

Refractive index of a solid is observed to have the same value along all directions. Comment on the nature of this solid. Would it show clevage property?

Classify the following solids in different categories based on the nature of intermolecular forces operating in them:
Potassium sulphate, tin, benzene, urea, ammonia, water, zinc
sulphate, graphite, rubidium, argon, silicon carbide.

Solid A is a very hard, electrical insulator in solid as well as in molten state and melts at extremely high temperature. What type of solid is it?

Ionic solids conduct electricity in liquid state but not in solid state. Explain.

What type of solids are electrical conductors, malleable and ductile?

Give the significance of a 'lattice point'.

Name the parameters that characterize a unit cell.

Distinguish between Hexagonal and monoclinic unit cells.

Distinguish between Face-centred and end-centred unit cells.

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For Daily Free Study Material Join wiredfaculty

The Solid State

If the radius of the octahedral void is r and radius of the atoms in close packing is R, derive relation between r and R.

Some More Questions From The Solid State Chapter

Why is glass considred a super-cooled liquid?

Refractive index of a solid is observed to have the same value along all directions. Comment on the nature of this solid. Would it show clevage property?

Classify the following solids in different categories based on the nature of intermolecular forces operating in them: Potassium sulphate, tin, benzene, urea, ammonia, water, zinc sulphate, graphite, rubidium, argon, silicon carbide.

Solid A is a very hard, electrical insulator in solid as well as in molten state and melts at extremely high temperature. What type of solid is it?

Ionic solids conduct electricity in liquid state but not in solid state. Explain.

What type of solids are electrical conductors, malleable and ductile?

Give the significance of a 'lattice point'.

Name the parameters that characterize a unit cell.

Distinguish between Hexagonal and monoclinic unit cells.

Distinguish between Face-centred and end-centred unit cells.

Mock Test Series

NCERT Sample Papers

Entrance Exams Preparation

Classify the following solids in different categories based on the nature of intermolecular forces operating in them:
Potassium sulphate, tin, benzene, urea, ammonia, water, zinc
sulphate, graphite, rubidium, argon, silicon carbide.