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The Solid State

Question
CBSEENCH12005449

Why is potassium chloride sometimes violet instead of pure white.

Solution
when a crystal of KCl is heated in an atomsphere of potassiuim vapour the Katoms lose electron to form K+ ions. The released electron diffuse into the crystal and occupy anionic site (F- centre)
These electron impart violet colour to the KCl crystal.