Sponsor Area

The D-And-f-Block Elements

Question
CBSEENCH12007217

What may be the possible oxidation states of the transition metals with the following d electronic configurations in the ground state of their atoms: 3d34s2,3d54s2 and 3d64s2. Indicative relative stability of oxidation states in each case.

Solution

(a) Configuration

3d34s2

3d5 4s2

3d6 4s2

(a) Stable oxidation state

+3, +3

+2, +7

+2, +8

The stability of any oxidation state of any element generally depends upon the electronic configuration of that particular ion. If any ion has stable configuration (d5, d10 etc.), the particular oxidation state will be more stable.