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The D-And-f-Block Elements

Question
CBSEENCH12007116

Compare the stability of +2 oxidation state for the elements of the first transition series.

Solution



In the beginning of 3d transition series, Sc2+ is virtually not known or in other words it is not stable in comparison to Sc3+, Ti2+, V2+, Cr2+ are known but less stable in comparison to their most common oxidation state of +3.
In the middle Mn2+, Fe2+, Co2+ are known and quite common. In fact Mn2+ and Mn7+ are most stable in Mn. Fe2+ is less stable in comparison to Fe3+ but is due to fact that Fe3+tends to loose one electron to aquire d5 structure which has extra stability. Co2+ is less stable as compared to Co3+. Ni2+ is most common and most stable among its +2, +3, +4 states. Cu2+ is more stable and is most common species as compared to Cu1+. At end Zn forms only Zn2+ which is highly stable as it has 3d10 structure.