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The D-And-f-Block Elements

Question
CBSEENCH12007188

What are interstitial compounds? What are their main characteristics?

Solution

In the crystal lattices of transition metals-small atoms like C, H, B, N etc. are trapped non-stoichiometrically. Such compounds are called interstitial compounds, e.g., TiC, Mn4N, Fe3H, TiH2 etc. Their main characteristics are:
(i)    They have high melting points than their metals.
(ii)    They become much harder (e.g., borides).
(iii)    Metallic conductivity is retained.
(iv)    They become chemically inert.
(v)    They become less malleable and ductile.