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The D-And-f-Block Elements

Question
CBSEENCH12007059

How would you convert potassium dichromate to potassium chromate?

Solution

i)When the aqueous solution of potassium dichromate is treated with calculated amount of KOH, potassium chromate is formed.

 K2Cr7O7 + 2KOH → 2K2CrO4 + H2O

ii) When an alkali is added to an orange red solution containing dichromate ions, a yellow solution is obtained due to the formation of chromate ions. 

 K2Cr2O7 + K2CO3 → 2 K2CrO4 + CO2