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The D-And-f-Block Elements

Question

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Give two properties in which interstitial compounds differ from its elements.

Solution

Interstitial compounds have modified properties than its elements e.g.

(i) They have high melting points, higher than those of pure metals.
(ii) They are very hard, some borides approach diamond in hardness.

Some More Questions From The d-And-f-Block Elements Chapter

Silver atom has a completely filled d orbitals (4d¹⁰) in its ground state. How can you say that it is a transition element?

In the series Sc (Z = 21) to Zn(Z = 30), the enthalpy of atomisation of zinc is the lowest i.e., 26, kJ mol. Why?

The E° (M²⁺/M) value for copper is positive (+ 0.34 V). What is possibility the reason for this?

How would you account for the irregular variation of ionisation enthalpies (first and second) in the first series of the transition elements?

Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?

Which is a stronger reducing agent Cr²⁺ or Fe²⁺ and why?

Explain why Cu⁺ ion is not stable in aqueous solutions?

Actinoid contraction is greater from element to element than lanthanoid contraction. Why?

On what ground can you say that scandium (Z = 21) is a transition element but zinc (Z = 30) is not?

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