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Equilibrium

Question
CBSEENCH11008410

Equimolar solutions of the following  were prepared in water separately which one of the solutions will record the highest pH? 

  • SrCl2

  • BaCl2

  • MgCl2

  • CaCl2

Solution

B.

BaCl2

As the basic nature increases
pH  of base > 7
pH of acid < 7
In alkaline earth metals on moving downward the size of cation increases, thus basicity increases. Hence, the increasing order or basicity is as:
MgCl2 < CaCl2 < SnCl2< BaCl2
Therefore, the solution of BaCl2 will record the highest pH.