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Equilibrium

Question
CBSEENCH11008405

If the concentration of OH- ions in the reaction Fe(OH)3 (s)  ⇌ Fe3+ (aq) + 3OH-(aq) is decreased by 1/4 times, then equilibrium concentration of Fe3+ will increase by 

  • 8 times

  • 16 times

  • 64 times

  • 4 times

Solution

C.

64 times

The concentration of solids taken to be unity.
Fe(OH)3 (s)  ⇌ Fe3+ (aq) + 3OH- (aq)
therefore,
K = [Fe3+][OH-]3
Hence, if OH- ion concentration is decreased by 1/4 times. then equilibrium concentration of Fe3+ will increase by 64 times.