Match List I (equation) with List II (types of the process) and select the correct option.
List I (Equations)
|
List II (Types of process)
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A |
KP > Q |
1 |
Non-spontaneous |
B |
ΔGo < RT In Q |
2 |
Equilibrium |
C |
KP = Q |
3 |
Spontaneous and endothermic |
D |
T> ΔH/ ΔS |
4 |
Spontaneous |
-
ABCD1234
-
A B C D 3 4 2 1 -
A B C D 4 1 2 3 -
A B C D 2 1 4 3
C.
A | B | C | D |
4 | 1 | 2 | 3 |
A) When KP > Q, the reaction goes in the forward direction, ie, the reaction is spontaneous.
B) Given ΔGo < RT lnQ, thus, ΔGo = + ve and hence, the reaction is non-spontaneous.
C) At equilibrium, Kp = Q
D) T > ΔH/ΔS or TΔS >ΔH
Thus condition is true for spontaneous endothermic reactions (as ΔG greater than equal to ΔH- TΔS)