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Organic Chemistry – Some Basic Principles And Techniques

Question
CBSEENCH11008280

Which of the statements is not true?

  • On passing H2S through acidified K2Cr2O7 solution, milky colour is observed.

  • Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis

  • Na2Cr2O7 solution in acidic medium is orange

  • K2Cr2O7 solution becomes yellow on increasing the pH beyond 7

Solution

B.

Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis

Being hygroscopic, sodium dichromate Na2Cr2O7 cannot be used in volumetric analysis. All other given statements are true.