-->

Redox Reactions

Question
CBSEENCH11008268

When Cl2 gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from

  • zero to +1 and zero to -5

  • zero to -1 and zero to +5

  • zero to -1 and zero to +5

  • zero to +1 and zero to -3

Solution

B.

zero to -1 and zero to +5

When chlorine gas reacts with hot and concentrated NaOH solution, it disproportionates into Chloride (Cl-) and Chlorate (ClO3-) ions. 
3 Cl with 0 on top subscript 2 space plus space stack 6 NaOH space with Hot space and space concentrated below rightwards arrow space 5 Na Cl with negative 1 on top space plus Na Cl with plus 5 on top straight O subscript 3 space plus 3 straight H subscript 2 straight O